Graeme,
In about 1941, the British started a new system of lotting empty fuzes, primers and tracers. As far as I'm aware the system was only used during the war and I suspect it was introduced due to the phenomenal output of some of the factories.
The system consists of two letters of the alphabet representing the series of the empty lot numbers:-
Letters AA represents Lots 1 to 10
Letters AB represents Lots 11 to 20, etc.
The letter I is not used
Once a group is completed, the letters increment until ZZ is reached. The letters are prefixed by a single number which indicates the year of manufacture.
Thus 4AS for a particular manufacturer means :-
Year: 1944
Group: AS, representing empty Lots 171 to 180.
With respect to your wartime 40mm cases, are any of them stamped with a broad arrow within a circle, hexagon or octagon?
TimG